He said: “I think we’ve got as good a chance as we have in any game. We’ve not started great within the group, we could have had a couple of better results and performances, probably.
“One, you’re away from home and two, you’re playing against a team that has got a level of player that is superior to you.
“But that’s never been an issue for us. Any time we have come up against the bigger nations we normally rise to the occasion.”
Miller was the last player to score for the Scots against the English at their national stadium in a 3-2 friendly defeat in August 2013.
The 36-year-old attacker said: “I felt in the last game, we were not really given much chance with the level of player you are coming up against and the fact it was at Wembley.
“Let’s be honest, England are not in a great shape at the moment, so there’s no reason why we can’t achieve a positive result.”